Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene.
نویسندگان
چکیده
The first nickel complex bearing a boryl moiety, (PNP)Ni[B(catechol)](PNP = N[2-P(CHMe(2))(2)-4-methylphenyl](2)(-)), has been prepared, structurally characterized, and analyzed by DFT; this rare species is shown to be a recyclable reagent for the borylation of bromobenzene, via an unusual cycle, by applying the ingredients catecholborane and NaBH(4).
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ورودعنوان ژورنال:
- Chemical communications
دوره 43 شماره
صفحات -
تاریخ انتشار 2007